Bromine (Br)

Atomic Number35
Atomic Mass79.904 u
CategoryDiatomic nonmetal
Electron Config[Ar] 3d¹⁰ 4s² 4p⁵
Appearancereddish-brown liquid
Density (STP)3120 g/L
Melting Point265.8 K
Boiling Point332 K
Electronegativity2.96 (Pauling)
Ionization Energy1139.9 kJ/mol
Atomic Radius115 pm
Crystal StructureBase Orthorhombic
Discovered ByAntoine Jérôme Balard (1826)

Brief Introduction

Bromine (Br) is a heavy, volatile, mobile, reddish-brown liquid at room temperature with a strong, disagreeable odor. It is one of only two elements that are liquid at standard conditions (the other being mercury). Key details about Bromine (Br) are as follows:

Uses: Used in flame retardants (though many brominated compounds are being phased out), agricultural fumigants and pesticides, water treatment and sanitization (bromine tablets for pools), oil and gas drilling fluids, pharmaceuticals, and in photographic film. Historically used in leaded gasoline (ethylene dibromide, now banned).

Production/Extraction: Extracted from brine (seawater, salt lakes, underground brines) through oxidation and distillation. Major producers include the United States, Israel (Dead Sea), and China. The Dead Sea and Arkansas brine wells are major sources.

History: Discovered independently by Antoine Jérôme Balard (1826) and Carl Jacob Löwig (1825). Balard published first and gets credit. Named from Greek "bromos" (stench) due to its strong, unpleasant odor.

Health Effects & Safety: Highly corrosive and toxic. Bromine vapor irritates eyes, respiratory system, and skin. Liquid bromine causes severe chemical burns. Some brominated compounds are neurotoxic or endocrine disruptors. Bromide ions were historically used as sedatives but can cause bromism (toxicity).

Price/Market: Price influenced by flame retardant regulations and agricultural demand. Environmental concerns about persistent brominated compounds affect market. Dead Sea production is economically significant for Israel.

Properties: Only nonmetallic element liquid at room temperature, high density for a nonmetal, readily evaporates (volatile), strong oxidizing agent, reacts with many elements, reddish-brown color in both liquid and vapor forms, and highly corrosive.

← Selenium (Se) · Krypton (Kr) →

Periodic Table