Gallium (Ga)
| Atomic Number | 31 |
|---|---|
| Atomic Mass | 69.7231 u |
| Category | Post-transition metal |
| Electron Config | [Ar] 3d¹⁰ 4s² 4p¹ |
| Appearance | silver-white |
| Density (STP) | 5904 g/L |
| Melting Point | 302.9146 K |
| Boiling Point | 2673 K |
| Electronegativity | 1.81 (Pauling) |
| Ionization Energy | 578.8 kJ/mol |
| Atomic Radius | 130 pm |
| Crystal Structure | Base Orthorhombic |
| Discovered By | Lecoq de Boisbaudran (1875) |
Brief Introduction
Gallium (Ga) is a soft, silvery metal that is liquid near room temperature (melts at 29.76°C) and has the largest liquid range of any element. It is primarily used in electronics and optoelectronics. Key details about Gallium (Ga) are as follows:
Uses: Critical for semiconductor devices (gallium arsenide GaAs in high-frequency electronics, solar cells, LEDs), integrated circuits, blue and violet LEDs and laser diodes (gallium nitride GaN), photovoltaic solar panels, and in some medical applications. Small amounts used in thermometers and heat transfer systems.
Production/Extraction: Produced as a byproduct of aluminum and zinc refining from bauxite. No primary gallium ores exist. China produces the majority of global gallium. Also recovered from coal fly ash.
History: Predicted by Dmitri Mendeleev in 1871 (as "eka-aluminum"). Discovered by Paul-Émile Lecoq de Boisbaudran in 1875 through spectroscopy of zinc blende. Named after Gallia (Latin for France), though some suggest a pun on Lecoq's name (Latin "gallus" = rooster/Lecoq).
Health Effects & Safety: Considered relatively non-toxic in metallic form, though safety data is limited. Gallium compounds can be toxic. Liquid gallium at body temperature is safe to handle briefly but stains skin and clothing. Some isotopes are radioactive.
Price/Market: Price subject to significant fluctuations. Growing demand from LED and semiconductor industries. Export restrictions by China have impacted global markets. Classified as a critical mineral for technology applications.
Properties: Melts in hand (29.76°C), remains liquid until 2204°C (largest liquid range), expands upon solidification (like water), wets glass and most materials, superconducting below 1.083 K, and exhibits +3 oxidation state primarily.
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