Niobium (Nb)
| Atomic Number | 41 |
|---|---|
| Atomic Mass | 92.906372 u |
| Category | Transition metal |
| Electron Config | [Kr] 4d⁴ 5s¹ |
| Appearance | gray metallic, bluish when oxidized |
| Density (STP) | 8570 g/L |
| Melting Point | 2750 K |
| Boiling Point | 5017 K |
| Electronegativity | 1.6 (Pauling) |
| Ionization Energy | 652.1 kJ/mol |
| Atomic Radius | 145 pm |
| Crystal Structure | Body-centered Cubic |
| Discovered By | Charles Hatchett (1801) |
Brief Introduction
Niobium (Nb) is a soft, gray, ductile transition metal with excellent superconducting properties and high melting point. It is chemically similar to tantalum. Key details about Niobium (Nb) are as follows:
Uses: Primarily used in high-strength low-alloy (HSLA) steels for pipelines, automotive, and construction (small amounts increase strength and toughness), superconducting magnets (MRI machines, particle accelerators), capacitors, and nickel-based superalloys for jet engines.
Production/Extraction: Extracted from pyrochlore and columbite ores. Brazil dominates global production (>90%), with Canada as a secondary source. Relatively easy to separate from tantalum compared to other metal pairs.
History: Discovered by Charles Hatchett in 1801 in a mineral from Massachusetts, originally named "columbium" (symbol Cb). Later confused with tantalum until proved distinct. IUPAC officially adopted "niobium" in 1950, though "columbium" persists in U.S. metallurgy. Named after Niobe (daughter of Tantalus in Greek mythology).
Health Effects & Safety: Considered relatively non-toxic and inert. No known biological role. Niobium dust may pose inhalation hazards. Generally safe to handle.
Price/Market: Moderate pricing; ferroniobium (iron-niobium alloy) is the main commercial form. Brazil's near-monopoly creates supply concentration concerns. Growing demand from steel industry and superconductor applications.
Properties: Excellent superconductor (highest critical temperature of elemental superconductors at 9.2 K), high melting point (2477°C), resistant to corrosion, ductile, forms protective oxide layer, exhibits primarily +5 oxidation state, and easily alloyed with steel.