Rhodium (Rh)
| Atomic Number | 45 |
|---|---|
| Atomic Mass | 102.905502 u |
| Category | Transition metal |
| Electron Config | [Kr] 4d⁸ 5s¹ |
| Appearance | silvery white metallic |
| Density (STP) | 12450 g/L |
| Melting Point | 2237 K |
| Boiling Point | 3968 K |
| Electronegativity | 2.28 (Pauling) |
| Ionization Energy | 719.7 kJ/mol |
| Atomic Radius | 135 pm |
| Crystal Structure | Face-centered Cubic |
| Discovered By | William Hyde Wollaston (1803) |
Brief Introduction
Rhodium (Rh) is a rare, silvery-white, hard, and highly reflective transition metal belonging to the platinum group. It is the most expensive precious metal and has exceptional catalytic properties. Key details about Rhodium (Rh) are as follows:
Uses: Primarily used in catalytic converters for automobiles (reduces nitrogen oxide emissions), in jewelry (rhodium plating for white gold and silver provides tarnish resistance and luster), in searchlights and mirrors (highly reflective coating), and as a catalyst in chemical synthesis.
Production/Extraction: Produced as a byproduct of platinum and nickel mining. South Africa produces about 80% of global supply, with Russia as a secondary source. Extremely rare—world production is only a few tens of tons annually.
History: Discovered by William Hyde Wollaston in 1803 in platinum ore from South America. Named from Greek "rhodon" (rose) due to the rose-red color of one of its chloride compounds.
Health Effects & Safety: Generally considered non-toxic and biologically inert. Some rhodium compounds can cause staining and allergic reactions. No known biological role. Safe for jewelry applications.
Price/Market: Extremely expensive and volatile pricing (often $10,000-$20,000+ per troy ounce, sometimes exceeding gold and platinum). Price driven by automotive catalytic converter demand and supply constraints. Supply concentration in South Africa creates geopolitical risks.
Properties: Highest reflectivity of any metal, excellent catalytic properties (especially for NOx reduction), extremely resistant to corrosion and oxidation, high melting point (1964°C), hard and durable, and exhibits primarily +3 oxidation state.
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