Chlorine (Cl)

Atomic Number17
Atomic Mass35.45 u
CategoryDiatomic nonmetal
Electron Config[Ne] 3s² 3p⁵
Appearancepale yellow-green gas
Density (STP)3.214 g/L
Melting Point171.6 K
Boiling Point239.11 K
Electronegativity3.16 (Pauling)
Ionization Energy1251.2 kJ/mol
Atomic Radius100 pm
Crystal StructureBase Orthorhombic
Discovered ByCarl Wilhelm Scheele (1774)

Brief Introduction

Chlorine (Cl) is a yellow-green, dense, toxic diatomic gas with a pungent, suffocating odor. It is highly reactive and is never found free in nature, but is common in compounds, especially salt (NaCl). Key details about Chlorine (Cl) are as follows:

Uses: Used for water purification and disinfection (swimming pools, drinking water), production of PVC (polyvinyl chloride) plastic, bleaching agents, solvents, pesticides, and many pharmaceuticals. Also used in paper and textile industries.

Production/Extraction: Produced industrially through electrolysis of brine (sodium chloride solution) via the chlor-alkali process, which simultaneously produces chlorine, hydrogen, and sodium hydroxide. Also produced via the electrolysis of molten salt.

History: Discovered by Carl Wilhelm Scheele in 1774, though he didn't recognize it as an element. Identified as an element by Humphry Davy in 1810 and named from Greek "chloros" (greenish-yellow). Used as a chemical weapon in WWI.

Health Effects & Safety: Highly toxic gas; even low concentrations irritate respiratory system and eyes. Liquid chlorine causes severe burns. Chlorine gas was used in chemical warfare. Chloride ions (Cl⁻) are essential for human physiology (stomach acid, electrolyte balance). Disinfection byproducts from chlorinated water raise minor health concerns.

Price/Market: Moderate pricing; produced in massive quantities globally. Market tied to PVC production and water treatment. Transportation and storage require special handling due to toxicity.

Properties: Strong oxidizing agent, characteristic yellow-green color, highly electronegative, reacts with most elements, denser than air, bleaching properties, and exists in multiple oxidation states in compounds.

← Sulfur (S) · Argon (Ar) →

Periodic Table