Cadmium (Cd)
| Atomic Number | 48 |
|---|---|
| Atomic Mass | 112.4144 u |
| Category | Transition metal |
| Electron Config | [Kr] 4d¹⁰ 5s² |
| Appearance | silvery bluish-gray metallic |
| Density (STP) | 8650 g/L |
| Melting Point | 594.22 K |
| Boiling Point | 1040 K |
| Electronegativity | 1.69 (Pauling) |
| Ionization Energy | 867.8 kJ/mol |
| Atomic Radius | 155 pm |
| Crystal Structure | Simple Hexagonal |
| Discovered By | Karl Samuel Leberecht Hermann (1817) |
Brief Introduction
Cadmium (Cd) is a soft, bluish-white, toxic transition metal that is chemically similar to zinc. It is highly corrosive to many metals and has environmental health concerns. Key details about Cadmium (Cd) are as follows:
Uses: Used in nickel-cadmium (NiCd) rechargeable batteries (declining due to toxicity concerns), pigments (cadmium yellow, cadmium red for artists' paints), coatings and plating (corrosion protection, now restricted), plastic stabilizers (PVC), and in certain metal alloys. Also used in control rods for nuclear reactors (high neutron absorption).
Production/Extraction: Produced almost entirely as a byproduct of zinc refining (cadmium occurs with zinc in ores). China, South Korea, and Japan are major producers. Cannot be economically mined independently.
History: Discovered by Friedrich Stromeyer in 1817 in Germany as an impurity in zinc carbonate. Named from Latin "cadmia" (calamine, zinc carbonate), which comes from Greek "kadmeia" (Cadmean earth).
Health Effects & Safety: Highly toxic heavy metal and human carcinogen. Accumulates in kidneys and liver, causing kidney disease, bone demineralization (itai-itai disease in Japan), and cancer. Major environmental pollutant (found in cigarette smoke, contaminated water and food). Use increasingly restricted by regulations (EU RoHS directive).
Price/Market: Moderate pricing as a byproduct metal. Market declining due to environmental regulations and replacement of NiCd batteries with lithium-ion technology. Disposal and recycling regulated due to toxicity.
Properties: Soft and ductile, low melting point (321°C), corrosion-resistant (protective oxide layer), strong neutron absorber, exhibits +2 oxidation state almost exclusively, and forms colorful compounds (yellow, orange, red pigments).
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