Palladium (Pd)
| Atomic Number | 46 |
|---|---|
| Atomic Mass | 106.421 u |
| Category | Transition metal |
| Electron Config | [Kr] 4d¹⁰ |
| Appearance | silvery white |
| Density (STP) | 12023 g/L |
| Melting Point | 1828.05 K |
| Boiling Point | 3236 K |
| Electronegativity | 2.2 (Pauling) |
| Ionization Energy | 804.4 kJ/mol |
| Atomic Radius | 140 pm |
| Crystal Structure | Face-centered Cubic |
| Discovered By | William Hyde Wollaston (1803) |
Brief Introduction
Palladium (Pd) is a soft, silvery-white transition metal belonging to the platinum group. It has the lowest melting point and density of the platinum group metals and has remarkable hydrogen absorption properties. Key details about Palladium (Pd) are as follows:
Uses: Primarily used in catalytic converters (especially for gasoline engines), electronics (multilayer ceramic capacitors, hybrid integrated circuits), dentistry (alloys for crowns and bridges), jewelry (white gold alloys), hydrogen purification and storage, and as a catalyst in organic chemistry (Suzuki and Heck reactions).
Production/Extraction: Produced primarily from nickel-copper sulfide ores in Russia and South Africa, with additional production from platinum ores. Russia and South Africa dominate supply. Also recovered from recycled catalytic converters.
History: Discovered by William Hyde Wollaston in 1803 in platinum ore, shortly after discovering rhodium. Named after the asteroid Pallas, which had been discovered in 1802. Wollaston initially sold it anonymously as a "new silver."
Health Effects & Safety: Generally considered non-toxic, though some people develop allergic reactions (especially to palladium in dental work and jewelry). Palladium compounds should be handled with care. No known biological role.
Price/Market: Price extremely volatile and has surged dramatically in recent years due to tightening emission standards increasing catalytic converter demand. Can exceed platinum and gold prices. Supply constraints and geopolitical factors (Russia, South Africa) significantly impact markets.
Properties: Absorbs up to 900 times its volume of hydrogen gas at room temperature (unique among metals), excellent catalytic properties, resistant to corrosion and oxidation, ductile and malleable, lowest melting point (1555°C) among platinum group metals, and exhibits primarily +2 and +4 oxidation states.
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