Thallium (Tl)
| Atomic Number | 81 |
|---|---|
| Atomic Mass | 204.38 u |
| Category | Post-transition metal |
| Electron Config | [Xe] 4f¹⁴ 5d¹⁰ 6s² 6p¹ |
| Appearance | silvery white |
| Density (STP) | 11850 g/L |
| Melting Point | 577 K |
| Boiling Point | 1746 K |
| Electronegativity | 1.62 (Pauling) |
| Ionization Energy | 589.4 kJ/mol |
| Atomic Radius | 190 pm |
| Crystal Structure | Simple Hexagonal |
| Discovered By | William Crookes (1861) |
Brief Introduction
Thallium (Tl) is a soft, gray post-transition metal that is not found free in nature. When isolated, it resembles tin, but discolors when exposed to air. It is highly toxic. Key details about Thallium (Tl) are as follows:
Uses: Used in electronics (photoelectric cells, infrared detectors), low-melting glass (for lenses), thallium-based high-temperature superconductors, and medical imaging (Thallium-201 stress tests). Historically used as rat poison and ant killer (banned in many countries).
Production/Extraction: Produced as a byproduct of lead and zinc refining. Not mined specifically for its own sake. Major producers include China, Kazakhstan, and Russia.
History: Discovered in 1861 by William Crookes via spectroscopy. Named from Greek "thallos" (green shoot or twig) due to its bright green spectral emission line. Isolated by Crookes and Claude-Auguste Lamy in 1862.
Health Effects & Safety: Extremely toxic (historically a favorite of poisoners due to being tasteless and odorless). Causes hair loss (alopecia), nerve damage, and death. Rapidly absorbed through skin. Strict safety protocols required.
Price/Market: Limited commercial market. Pricing is variable and negotiated directly between suppliers and consumers. Demand is driven by specialized optics and electronics.
Properties: Very soft and malleable (can be cut with a knife), tarnishes rapidly to a dark gray oxide, toxic, exhibits +1 and +3 oxidation states, and melts at 304°C.
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