Chromium (Cr)
| Atomic Number | 24 |
|---|---|
| Atomic Mass | 51.99616 u |
| Category | Transition metal |
| Electron Config | [Ar] 3d⁵ 4s¹ |
| Appearance | silvery metallic |
| Density (STP) | 7190 g/L |
| Melting Point | 2180 K |
| Boiling Point | 2944 K |
| Electronegativity | 1.66 (Pauling) |
| Ionization Energy | 652.9 kJ/mol |
| Atomic Radius | 140 pm |
| Crystal Structure | Body-centered Cubic |
| Discovered By | Louis Nicolas Vauquelin (1797) |
Brief Introduction
Chromium (Cr) is a hard, lustrous, steel-gray transition metal that takes a high polish and is highly resistant to tarnishing and corrosion. It is the hardest metal element. Key details about Chromium (Cr) are as follows:
Uses: Primarily used in stainless steel (corrosion resistance), chrome plating (decorative and protective coatings), pigments (chrome yellow, chrome green), leather tanning (chromium salts), refractory materials, and in superalloys for high-temperature applications.
Production/Extraction: Extracted from chromite ore (FeCr₂O₄) through smelting to produce ferrochromium, or through reduction processes for pure chromium. South Africa, Kazakhstan, and India hold major reserves and production capacity.
History: Discovered in 1797 by Louis-Nicolas Vauquelin in a mineral sample from Siberia (Siberian red lead, later named crocoite). Named from Greek "chroma" meaning "color" due to the many colorful compounds chromium forms.
Health Effects & Safety: Trivalent chromium (Cr³⁺) is an essential trace nutrient involved in glucose metabolism. Hexavalent chromium (Cr⁶⁺) is highly toxic, carcinogenic, and a serious environmental hazard (famously depicted in "Erin Brockovich"). Industrial exposure requires strict safety controls.
Price/Market: Ferrochromium prices tied to stainless steel production. Supply concentrated in a few countries creates geopolitical concerns. Environmental regulations impact chromium processing industries.
Properties: Extremely hard and brittle, resists tarnishing and corrosion, exhibits multiple oxidation states (+2 to +6), forms colorful compounds, high melting point (1907°C), and passivates (forms protective oxide layer) rapidly.
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