Sulfur (S)

Atomic Number16
Atomic Mass32.06 u
CategoryPolyatomic nonmetal
Electron Config[Ne] 3s² 3p⁴
Appearancelemon yellow sintered microcrystals
Density (STP)1960 g/L
Melting Point388.36 K
Boiling Point717.8 K
Electronegativity2.58 (Pauling)
Ionization Energy999.6 kJ/mol
Atomic Radius100 pm
Crystal StructureFace-centered Orthorhombic
Discovered ByAncient China (-500)

Brief Introduction

Sulfur (S) is a bright yellow, brittle nonmetal that is essential for life and has been known since ancient times. It exists in multiple allotropic forms and is found both free in nature and in many minerals. Key details about Sulfur (S) are as follows:

Uses: Primarily used to produce sulfuric acid (the most widely produced chemical), in fertilizers, petroleum refining (removing sulfur from fuels), vulcanization of rubber, gunpowder, matches, fungicides, and in the paper industry. Also used in pharmaceuticals and detergents.

Production/Extraction: Extracted from underground deposits via the Frasch process (using superheated water), recovered from natural gas and petroleum refining (removing H₂S), and mined from volcanic regions. Major producers include the U.S., Russia, and Canada.

History: Known since prehistoric times; mentioned in ancient texts including the Bible (as "brimstone"). Used in ancient rituals, fumigation, bleaching, and medicine. Recognized as an element by Antoine Lavoisier in 1777.

Health Effects & Safety: Elemental sulfur has low toxicity and is used in traditional medicine and skin treatments. Sulfur dioxide (SO₂) is a toxic irritant and major air pollutant causing acid rain. Hydrogen sulfide (H₂S) is extremely toxic and flammable. Sulfur is essential for amino acids (cysteine, methionine) and proteins.

Price/Market: Price influenced by petroleum refining activity (recovered sulfur is a byproduct). Oversupply in recent years has depressed prices. Essential for global agriculture through sulfuric acid and phosphate fertilizers.

Properties: Bright yellow in most forms, exists in multiple allotropes (rhombic, monoclinic, plastic), poor conductor of heat and electricity, forms long-chain molecules when melted, burns with a blue flame producing SO₂, and exhibits multiple oxidation states.

← Phosphorus (P) · Chlorine (Cl) →

Periodic Table